Also known by her nickname Lily, Alizée started dancing early in her life,^[6] and by age four was already proficient. A year later, she was enrolled in Corsica's renowned dance school, École du Spectacle de Monique Mufraggi, and trained there until she was 15.^[7] In 1995, at the age of eleven, she won a coloring competition organized by Air Outre Mer, a former French airline now partly acquired by Swissair. Her design won first prize alizee sexy photos and was reproduced on the cabin of one of the airline's aircraft. The aircraft was subsequently named after her and for her efforts, Alizée won a trip to the Maldives.

Another track from the album, Fifty-Sixty, was leaked two months before the album was released. Though the song was not mentioned by name, the leak was confirmed in a press release which revealed the title and release schedule of the album.^[32] Fifty-Sixty later launched as the second single from the album in February 2008. The lyrics to Fifty-Sixty tell, in personal and metaphorical manner, of a young model under the guidance of Andy Warhol, possibly inspired by real-life story of Edie Sedgwick. The song ends with a reiteration of how she foolishly believed Andy that she was the most beautiful model of all. Three music videos will be released naked lolitas for the single^[33] - one for the album version of the song and the other two for two remixes.^[34]The first of the videos was released on May 5, 2008.^[35] For the purposes of promotion of the single and the music videos, a website (www.psychedeclips.com) and a MySpace page (www.myspace.com/psychedeclips) are being created.^[34].

A live CD and DVD, titled "Alizée En Concert"—comprising of selected performances from her tour—was launched a year later in the fall of 2004.^[17] The audio CD contained tracks, taken from her two studio albums. The DVD featured video footage of the same performances as on the CD, along with laryache bonus footage of her rehearsals.

After a four year hiatus, a time spent out of the media limelight, Alizée returned in December 2007 with a new album, "Psychédélices", the first one to be made without the creative supervision of her former mentor, Mylène Farmer. The album, which features 11 tracks,^[21] was made available for alolita pics digital downloads November 26, 2007,^[22] with a full release on December 3, 2007^[23][5] under the RCA Records label.^[24] The album includes collaborations with Bertrand Burgalat, Daniel Darc, Oxmo Puccino, Jérémy Chatelain,^[25] Michel-Yves Kochmann, and Jean Fauque.^[26]

Alizée debuted in 2000 with the album Gourmandises. It went on to become a hit both in Europe and outside. The album reached top five in charts in France, Germany, Mexico, Asian Countries and others. It was followed up with a studio album in 2003, Mes Courants Électriques, and a live album—Alizée En Concert—in 2004.