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In March 2008 Alizée visited México for the first time in a short promotional tour, on March 5 she was supposed to hold her second ever public autograph session of her career but it was cancelled due to problems with the store's security, Alizée held an improvised press conference to apologise with Mexico and all her fans as well as stating it was not her fault.^{sexy alizee-lolita lyrics class="reference">[39]} Sony BMG México also released an statement saying it was not Alizée's fault, and it was the store who had problems with the security and they didn't expect so many people, fences were broken and kids were in danger. Alizée also promised to mend this by having another autograph session by the time she visits the country later this year.^[40] She also stated that her tour will start on May 18 in Moscow, followed by concerts in México and then France.^[41][42] She also commented that piracy in music has two sides "one good" and "one bad" saying that sometimes it's good because her music reaches places that she never thought to reach.^[43] After the success of Alizée's tour in Mexico and in an attempt to amend the damage caused during her first promotional visit, Alizée announced an autograph session with fans on 26th June 2008 in Mexico City, over three-hundred CDs were signed and the the record label executives of Sony BMG México presented a Gold certification for shipments over 50,000 copies of "Psychédélices - Mexican Tour Edition".^[44] The fourth single to be lifted from "Psychédélices" in Mexico was Madonna's cover, "La Isla Bonita", so far it has gone on to become Alizée's first top ten on the airplay chart.^[45]

The compilation was re-released in early 2007 in Mexico by Universal music as a CD+DVD release,^[18] following the featuring photos de Nina-Friederike Gnädig nue of the songs in local radio stations. With the re-release and renewed interest, the songs climbed up the music charts in the country. The album became a hit, peaking at number four in the International Chart on May 28, 2007,^[19] and number eight on the main albums chart.^[20]

The first single from the album was Mademoiselle Juliette.^[27][28] It was released on September 30, 2007.^[28] It was accidentally released early on the Virgin Megastore website on September 23, 2007,^[29]^{alizee' walpaper id="cite_ref-29" class="reference">[30]} but was taken down later citing an error on the part of Virgin Music, France. The single was later made available in online music stores as well as radio stations,^[28][26] and went on to capture the #13 spot on the legal music downloads charts.^[5][23] To promote the single, Alizée appeared on the French radio station, NRJ, on September 27, 2007.^[27][28] The video for the single was released for broadcast on November 19, 2007,^[31] though it was made available on MSN France on November 16, 2007. It was released on physical media, available as a CD or Vinyl, on January 21, 2008.